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Which of the following is the strongest oxidizing agent?


A) Br2(l)
B) Au3+(aq)
C) Ag(s)
D) Br⁻(aq)
E) Au(s)

F) A) and D)
G) A) and E)

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Determine the redox reaction represented by the following cell notation: Mg(s) ∣ Mg2+(aq) Determine the redox reaction represented by the following cell notation:  Mg(s)  ∣ Mg<sup>2+</sup>(aq)    Cu<sup>2+</sup>(aq)  ∣ Cu(s)  A)  Cu(s)  + Mg<sup>2+</sup>(aq)  → Mg(s)  + Cu<sup>2+</sup>(aq)  B)  Mg(s)  + Cu<sup>2+</sup>(aq)  → Cu(s)  + Mg<sup>2+</sup>(aq)  C)  2Mg(s)  + Cu<sup>2+</sup>(aq)  → Cu(s)  + 2Mg<sup>2+</sup>(aq)  D)  2Cu(s)  + Mg<sup>2+</sup>(aq)  → Mg(s)  + 2Cu<sup>2+</sup>(aq)  E)  3Mg(s)  + 2Cu<sup>2+</sup>(aq)  → 2Cu(s)  + 3Mg<sup>2+</sup>(aq) Cu2+(aq) ∣ Cu(s)


A) Cu(s) + Mg2+(aq) → Mg(s) + Cu2+(aq)
B) Mg(s) + Cu2+(aq) → Cu(s) + Mg2+(aq)
C) 2Mg(s) + Cu2+(aq) → Cu(s) + 2Mg2+(aq)
D) 2Cu(s) + Mg2+(aq) → Mg(s) + 2Cu2+(aq)
E) 3Mg(s) + 2Cu2+(aq) → 2Cu(s) + 3Mg2+(aq)

F) A) and C)
G) B) and C)

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Identify the battery that is used as a common flashlight battery.


A) dry-cell battery
B) lithium-ion battery
C) lead-acid storage battery
D) NiCad battery
E) fuel cell

F) B) and C)
G) C) and E)

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Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25 °C: Al(s) ∣ Al3+(aq, 0.115 mol L-1) Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25 °C: Al(s)  ∣ Al<sup>3+</sup>(aq, 0.115 mol L<sup>-1</sup>)    Al<sup>3+</sup>(aq, 3.89 mol L<sup>-1</sup>)  ∣ Al(s)  E°(Al<sup>3+</sup>/Al)  = -1.66 V A)  +1.66 V B)  +0.060 V C)  0.00 V D)  +0.090 V E)  +0.030 V Al3+(aq, 3.89 mol L-1) ∣ Al(s) E°(Al3+/Al) = -1.66 V


A) +1.66 V
B) +0.060 V
C) 0.00 V
D) +0.090 V
E) +0.030 V

F) A) and B)
G) A) and C)

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Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 2 5°C. (The equation is balanced.) Pb(s) + Br2(l) → Pb2+(aq) + 2 Br⁻(aq) Pb2+(aq) + 2 e⁻ → Pb(s) E° = -0.13 V Br2(l) + 2 e⁻ → 2 Br⁻(aq) E° = +1.07 V


A) +1.20 V
B) +0.94 V
C) -0.94 V
D) -1.20 V
E) -0.60 V

F) B) and E)
G) A) and C)

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Describe how water can be made to be a good conductor of electrical current.


A) use pure water
B) heat the water
C) add salt
D) chill the water
E) vaporize the water

F) B) and C)
G) All of the above

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Use the provided reduction potentials to calculate ΔrG° for the following redox reaction: 2Al(s) + 3Mg2+(aq) → 2Al3+(aq) + 3Mg(s) E°(Al3+/Al) = -1.66 V and E°(Mg2+/Mg) = -2.37 V


A) +4.1 × 102 kJ mol-1
B) +1.4 × 102 kJ mol-1
C) -2.3 × 102 kJ mol-1
D) -7.8 × 102 kJ mol-1
E) +6.8 × 102 kJ mol-1

F) None of the above
G) A) and E)

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Which of the following reactions would be the most spontaneous at 298 K?


A) A + 2 B → C; E°cell = +0.98 V
B) A + B → 2 C; E°cell = -0.030 V
C) A + B → 3 C; E°cell = +0.15 V
D) A + B → C; E°cell = +1.22 V
E) A + B → C; E°cell = -1.22 V

F) B) and E)
G) B) and D)

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Identify the battery that is in most automobiles.


A) dry-cell battery
B) lithium-ion battery
C) lead-acid storage battery
D) NiCad battery
E) fuel cell

F) A) and B)
G) A) and C)

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Which of the following metals will dissolve in nitric acid but not hydrochloric acid?


A) Cd; E°(Cd2+/Cd) = -0.40V
B) Cr; E°(Cr3+/Cr) = -0.73V
C) Mn; E°(Mn2+/Mn) = -1.18V
D) Ag; E°(Ag+/Ag) = +0.80V
E) Al; E°(Al3+/Al) = -1.66V

F) None of the above
G) B) and E)

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Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25 °: Cu(s) ∣ Cu2+(aq, 0.0032 mol L-1) Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25 °: Cu(s)  ∣ Cu<sup>2+</sup>(aq, 0.0032 mol L<sup>-1</sup>)    Cu<sup>2+</sup>(aq, 4.48 mol L<sup>-1</sup>)  ∣ Cu(s)  E°(Cu<sup>2+</sup>/Cu)  = +0.34 V A)  0.00 V B)  +0.093 V C)  +0.34 V D)  +0.186 V E)  +0.052 V Cu2+(aq, 4.48 mol L-1) ∣ Cu(s) E°(Cu2+/Cu) = +0.34 V


A) 0.00 V
B) +0.093 V
C) +0.34 V
D) +0.186 V
E) +0.052 V

F) B) and C)
G) C) and E)

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Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25 °C. (The equation is balanced.) Sn(s) + 2Ag⁺(aq) → Sn2+(aq) + 2Ag(s) Sn2+(aq) + 2 e⁻ → Sn(s) E° = -0.14 V Ag⁺(aq) + e⁻ → Ag(s) E° = +0.80 V


A) +1.74 V
B) +0.94 V
C) +1.08 V
D) -1.08 V
E) -1.74 V

F) None of the above
G) B) and E)

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Determine which of the following pairs of reactants will result in a spontaneous reaction at 25 °C.


A) Pb2+(aq) + Cu(s) ; if E°(Pb2+/Pb) = -0.13V and E°(Cu2+/Cu) = +0.16V
B) Ag+(aq) + Br⁻(aq) ; if E°(Ag+/Ag) = 0.80V and E°(Br2/Br-) = +1.09V
C) Li+(aq) + Al(s) ; if E°(Li+/Li) = -3.04V and E°(Al3+/Al) = -1.66V
D) Fe3+(aq) + Ni(s) ; if E°(Fe3+/Fe) = -0.04V and E°(Ni2+/Ni) = -0.23V
E) Cd2+(aq) + I-(aq) ; if E°(Cd2+/Cd) = -0.40V and E°(I2/I-) = + 0.54V

F) B) and E)
G) None of the above

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For the galvanic cell reaction, expressed below using shorthand notation, what half-reaction occurs at the cathode? Zn(s) ∣ Zn2+(aq) ∣∣ Ni2+(aq) ∣ Ni(s)


A) Zn(s) → Zn2+(aq) + 2 e-
B) Zn2+(aq) + 2 e- → Zn(s)
C) Ni(s) → Ni2+(aq) + 2 e-
D) Ni2+(aq) + 2 e- → Ni(s)

E) A) and C)
F) All of the above

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What is the reducing agent in the redox reaction represented by the following cell notation? Ni(s) ∣ Ni2+(aq) What is the reducing agent in the redox reaction represented by the following cell notation?  Ni(s)  ∣ Ni<sup>2+</sup>(aq)    Ag<sup>+</sup>(aq)  ∣ Ag(s)  A)  Ni(s)  B)  Ni<sup>2+</sup>(aq)  C)  Ag<sup>+</sup>(aq)  D)  Ag(s)  E)  Pt(s) Ag+(aq) ∣ Ag(s)


A) Ni(s)
B) Ni2+(aq)
C) Ag+(aq)
D) Ag(s)
E) Pt(s)

F) A) and E)
G) None of the above

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Use the standard half-cell potentials listed below to calculate the standard cell potential for the following reaction occurring in an electrochemical cell at 25°C. (The equation is balanced.) Br2(l) + 2Cl-(aq) → 2Br-(aq) + Cl2 (g) Br2(l) + 2 e → 2Br-(aq) E°= 1.09 V 2Cl- (aq) → Cl2(g) + 2 e - E°= -1.36 V


A) +0.93 V
B) +2.24 V
C) +2.45 V
D) +5.47 V
E) +0.67 V

F) A) and C)
G) All of the above

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A galvanic cell consists of a Zn2+/ Zn half-cell and a standard hydrogen electrode. If the Zn2+/ Zn half-cell standard cell functions as the anode, and the standard cell potential is 0.76 V, what is the standard reduction potential for the Zn2+/ Zn half-cell?


A) -0.76 V
B) -0.38 V
C) +0.38 V
D) +0.76 V

E) None of the above
F) A) and B)

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Explain the significance of the standard hydrogen electrode (SHE) in the tabulation of standard reduction potentials of other species.

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The SHE is used to construct an electroc...

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Which of the following is TRUE about standard electrode potentials?


A) E°cell is negative for spontaneous reactions.
B) Electrons will flow from a more positive electrode to a more negative electrode.
C) The electrode potential of the standard hydrogen electrode is exactly zero.
D) E°cell is the sum between standard reduction potentials of the anode and the cathode.
E) The electrode in any half-cell with a greater tendency to undergo reduction is negatively charged relative to the standard hydrogen electrode and therefore has E° < 0.

F) C) and D)
G) B) and E)

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What is undergoing reduction in the redox reaction represented by the following cell notation? Pb(s) ∣ Pb2+(aq) What is undergoing reduction in the redox reaction represented by the following cell notation? Pb(s)  ∣ Pb<sup>2+</sup>(aq)    H<sup>+</sup>(aq)  ∣ H<sub>2</sub>(g)  ∣ Pt(s)  A)  H<sub>2</sub>(g)  B)  H<sup>+</sup>(aq)  C)  Pb<sup>2+</sup>(aq)  D)  Pb(s)  E)  Pt(s) H+(aq) ∣ H2(g) ∣ Pt(s)


A) H2(g)
B) H+(aq)
C) Pb2+(aq)
D) Pb(s)
E) Pt(s)

F) A) and C)
G) D) and E)

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